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Standard peptide/protein practice is: store lyophilized material refrigerated or frozen, minimize freezethaw cycles after reconstitution, and use refrigerated liquid stocks within defined labspecific timelines

Administration of branched-chain amino acids during sustained exerciseeffects on performance and on plasma concentration of some amino acids

Trends Neurosci 30:228235 Svenningsson P, Nishi A, Fisone G et al (2004) DARPP-32: an integrator of neurotransmission

But the bottom line is that it really is a matter of preference

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